Flashdevelop
I'm still playing around with Flex/flash and learning some new tricks. I decided to try the open source version of Flex/Flash, FlashDevelop. It basically is just the IDE for the Flex SDK. I have to say I find it much better, at least for coding. The intellisense is great.
Here are some instructions:
http://www.britishideas.com/2008/02/27/first-steps-with-flash-using-the-flex-3-sdk/